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Scavenging of 1, 4-biradicals by bis (acetylacetonato) copper (II). The importance of paramagnetic effects

JC Scaiano, CWB Lee, YL Chow…

文献索引:Scaiano, J. C.; Lee, Carolyn W. B.; Chow, Yuan L.; Marciniak, Bronislaw Journal of Physical Chemistry, 1982 , vol. 86, # 13 p. 2452 - 2455

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被引用次数: 9

摘要

Results Laser Flash Photolysis. Our experiments were carried out under oxygen-free conditions using the pulses from a nitrogen laser (337.1 nm, 8 ns, up to 10 mJ) for excitation. Biradical absorptions (Scheme I) were monitored at 415 nm. 21 The biradical lifetime, TB, is 97 ns in methanol and shorter in the other solvents e~ amined.~,~~ The concen-