The Substituent Effect. XIII. Solvolysis of 1-(7-Substituted 2-Fluorenyl) ethyl Chlorides and Alkaline Hydrolysis of Ethyl 7-Substituted 2-Fluorenecarboxylates

Y Tsuno, Y Tairaka, M Sawada, T Fujii…

文献索引：Tsuno,Y. et al. Bulletin of the Chemical Society of Japan, 1978 , vol. 51, p. 601 - 607

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被引用次数: 9

摘要

Two sets of rate constants for (i) solvolysis of 1-(7-substituted 2-fluorenyl) ethyl chlorides in both 90 and 80% aqueous acetone and (ii) alkaline hydrolysis of ethyl 7-substituted 2- fluorenecarboxylates in 85% aq EtOH have been determined. Both substituent effects could be correlated excellently with the LArSR relationship; the resulting r+ values (0.82 and 0.47, respectively) were comparable with the r+'s in the corresponding biphenylyl system under ...