Phenyl tributylstannyl selenide as a promising reagent for introducion of the phenylseleno group

Y Nishiyama, H Kawamatsu, S Funato…

文献索引：Nishiyama, Yutaka; Kawamatsu, Hiroaki; Funato, Saori; Tokunaga, Keiji; Sonoda, Noboru Journal of Organic Chemistry, 2003 , vol. 68, # 9 p. 3599 - 3602

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被引用次数: 46

摘要

A new synthetic method of organoselenium compounds has been developed. When phenyl tributylstannyl selenide (PhSeSnBu3) was allowed to react with acyl or aroyl chlorides in the presence of a catalytic amount of a palladium complex such as Pd (PPh3) 4, Se-phenyl selenol esters were obtained in moderate to good yields. Similarly, the palladium complex catalyzed the reaction of PhSeSnBu3 with α-halo carbonyl compounds to afford the ...