Journal of Organometallic Chemistry

Reactivite des organostanniques allyliques vis-a-vis des derives halogenes: aspects synthetiques et mecanisme

J Grignon, C Servens, M Pereyre

文献索引：Grignon,J. et al. Journal of Organometallic Chemistry, 1975 , vol. 96, p. 225 - 235

被引用次数: 107

摘要

Abstract Allylic organotin compounds react with numerous organic halides by a substitution pathway with complete allylic shift. The radical chain mechanism proposed is supported by the reactivity sequences of halides, the stereochemistry, the influence of radical initiators or inhibitors, rearrangement, polar effects and the side products.