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Ring-expanding olefin metathesis: A route to highly active unsymmetrical macrocyclic oligomeric co-salen catalysts for the hydrolytic kinetic resolution of epoxides

X Zheng, CW Jones, M Weck

文献索引:Warwel, Siegfried; Kaetker, Hans Synthesis, 1987 , # 10 p. 935 - 937

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被引用次数: 116

摘要

... Chiral epoxides are among the most versatile building blocks for modern asymmetric organic synthesis due to the potential for the facile stereospecific ... 8,10 Using water as the nucleophile and chiral Co(III)-salen complexes (eg, 1) as the catalyst, the hydrolytic kinetic resolution ...