Modification of face selectivity by inclusion in cyclodextrins
…, NJ Turro, J Silver, WJ Le Noble
文献索引：Chung, Wen-Sheng; Turro, Nicholas J.; Silver, Jack; Le Noble, William J. Journal of the American Chemical Society, 1990 , vol. 112, # 3 p. 1202 - 1205
Abstract The photocycloadditions of 5-X-adamantan-2-011s (5-X-AD, where X= F, CI, Br, OH, Ph, and t-Bu) with fumaronitrile have been studied in acetonitrile and in aqueous solutions. When X is CI, Br, Ph, or t-Bu, irradiation of an aqueous solution containing P- cyclodextrin (b-CD) leads to a dramatic reversal in face selectivity compared to that found in acetonitrile and water; however, there is no significant change in product ratio compared ...
