5, 10, 15, 20-Tetraphenylporphyrinatorhodium (III) iodide catalyzed cyclopropanation reactions of alkenes using glycine ester hydrochloride

AGM Barrett, DC Braddock, I Lenoir…

文献索引：Barrett, Anthony G. M.; Braddock, D. Christopher; Lenoir, Isabelle; Tone, Hitoshi Journal of Organic Chemistry, 2001 , vol. 66, # 24 p. 8260 - 8263

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被引用次数: 42

摘要

The metal complex catalyzed reaction of an alkene with an R-diazo ester is an efficient method for the preparation of cyclopropane derivatives. 1 However, since diazo compounds are unstable intermediates, the use of this method for the preparation of cyclopropanecarboxylates is fraught with hazards on a large scale. In consequence, we sought to explore the possibility of generating cyclopropanecarboxylate esters from ...