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Tetrahedron letters

A novel approach to α-keto acid derivatives via palladium-catalyzed arylation and vinylation of methyl α-methoxyacrylate

S Cacchi, PG Ciattini, E Morera, G Ortar

文献索引:Cacchi, Sandro; Ciattini, Pier Giuseppe; Morera, Enrico; Ortar, Giorgio Tetrahedron Letters, 1987 , vol. 28, # 26 p. 3039 - 3042

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被引用次数: 33

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Methyl α-methoxyacrylate reacts stereoselectively with aryl iodides and vinyl triflates under palladium catalysis to give enol ethers of arylpyruvates and of β,γ-unsaturated α-keto esters in good to moderate yields. ... By the palladium catalysis methyl α-methoxyacrylate reacts with aryl iodides ...