Organic letters

Direct Use of Esters in the Mukaiyama Aldol Reaction: A Powerful and Convenient Alternative to Aldehydes

Y Inamoto, Y Nishimoto, M Yasuda, A Baba

文献索引：Inamoto, Yoshihiro; Nishimoto, Yoshihiro; Yasuda, Makoto; Baba, Akio Organic Letters, 2012 , vol. 14, # 4 p. 1168 - 1171

全文：HTML全文

被引用次数: 14

摘要

An indium triiodide catalyst promoted the direct transformation from esters to β- hydroxycarbonyl compounds using hydrosilanes and silyl enolates by a one-stage process. Various esters were applicable, and the high chemoselectivity of this system brings compatibility to many functional groups: alkenyl, alkynyl, chloro, and hydroxy.