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Convergent Functional Groups. 16. Hydrolysis of Phosphate Triesters by a Novel Cleft. Influence of Binding on Overall Rate Acceleration

BL Tsao, RJ Pieters, JJ Rebek

文献索引:Journal of the American Chemical Society, , vol. 117, # 8 p. 2210 - 2213

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被引用次数: 22

摘要

... 0002-786319511517-2210$09.00/0 0 1995 American Chemical Society ... The chemical shifts of the products were compared to ... This also allowed us to substitute values for kl and k2 obtained using Cu(bpy) 2 into eq I in order to determine rate constants, kj and k,. describing ...