Photochemistry of perfluoroalkyl and perfluoroacyl N-chloramines. Reactions of N-chloramines and N-chlorimines in the presence of mercury

GH Sprenger, JM Shreeve

文献索引：Sprenger,G.H.; Shreeve,J.M. Journal of the American Chemical Society, 1974 , vol. 96, p. 1770 - 1775

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被引用次数: 8

摘要

Abstract: Photolysis of perfluoroalkyl (fluoroformy1) and bis (fluoroformy1) N-chloramines neat or with other similarly substituted chloramines resulted in the formation of a new family of hydrazines which includes CFS-(FCO) NN (FCO) CF,,(FCO)? NN (FCO),,(CF3)? NN (FCO) CF,,(CF3) 2NN (FC0> 2, and CFS (FCO) NN (FCO) Z. With CF3 (FCO) NCl, CO and SOn inserted into the nitrogen-chlorine bond to give CFa (FCO) NC (O) Cl and the ...