The Journal of Organic Chemistry

Notes: Fluoroolefins. VIII. The Preparation of 2-Perfluoroalkyl-1, 3-butadienes

R Richardson, P Tarrant

文献索引：Richardson,R.D.; Tarrant,P. Journal of Organic Chemistry, 1960 , vol. 25, p. 2254 - 2256

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被引用次数: 6

摘要

Preparation of the methylwinylperJEuoroalky1 carbinol. The vinyl magnesium chloride was prepared in tetrahydrofuran solvent by the method of Ramsden, et. al. 3 Methyl perfluoroalkyl ketone was added dropwise to the stirred solution of vinyl magnesium chloride at such a rate that the temperature of the reaction mixture did not rise above 50'. The mixture was stirred 1 to 2 hr. and allowed to stand overnight. The Grignard ...