Phototransformation of Perchlorate to Chloride in the Presence of Polysilanes

…, A Halasz, C Beaulieu, S Thiboutot, G Ampleman…

文献索引：Lazar, Carmen; Halasz, Annamaria; Beaulieu, Chantale; Thiboutot, Sonia; Ampleman, Guy; Hawari, Jalal Australian Journal of Chemistry, 2007 , vol. 60, # 11 p. 857 - 861

全文：HTML全文

被引用次数: 2

摘要

Abstract Perchlorate is a uniquely stable chemical described as an emerging thyroid disrupting agent that is presently detected in several terrestrial and aquatic matrices. The present study was undertaken to deoxygenate perchlorate to the chloride anion photolytically in the presence of dodecamethylcyclohexasilane (Me 2 Si) 6 1. It is found that photolysis of 1 in the presence of dry NaClO 4 in tetrahydrofuran (THF) at 254 nm leads to ...