Journal of organometallic chemistry

Allylation of quinones by allylic indium reagents

S Araki, N Katsumura, Y Butsugan

文献索引：Araki, Shuki; Katsumura, Nobuhito; Butsugan, Yasuo Journal of Organometallic Chemistry, 1991 , vol. 415, # 1 p. 7 - 24

全文：HTML全文

被引用次数: 34

摘要

Abstract Allylation of a variety of quinones by allylic indium sesquihalides was studied. Reactions of unsubstituted p-benzoquinone with allylindium, prenylindium, and geranylindium reagents gave, after oxidation with silver oxide, the corresponding allylated quinones in good yields. These reactions appear to proceed via 1, 2-addition of the allylic indium reagents at the γ-carbon followed by [3, 3] sigmatropic rearrangement. Substituted ...