Aluminum chloride catalyzed reaction of acetanilide with pivalyl chloride

P Maslak, PE Fanwick, RD Guthrie

文献索引：Maslak, Przemyslaw; Fanwick, Phillip E.; Guthrie, Robert D. Journal of Organic Chemistry, 1984 , vol. 49, # 4 p. 655 - 659

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被引用次数: 7

摘要

Kinetics. Buffer solutions (2.5 mL) were thermostated in a 10-mm cuvet in the constant- temperature cell holder of a Cary 16 or Beckman DB spectrophotometer, at 25.0 i 0.1" C. To initiate reaction, 10 pL of a stock solution of substrate were injected with an Eppendorf pipet. Absorbances at 390 nm were collected to 80% reaction, the final absorbance was read after 10 half-life times, and first-order rate constants were calculated by a nonlinear least- ...