Silatropic carbonyl ene cyclizations in the synthesis of pseudosugars and hydroxylated piperidines

J Robertson, PM Stafford, SJ Bell

文献索引：Robertson, Jeremy; Hall, Michael J.; Stafford, Petra M.; Green, Stuart P. Organic and Biomolecular Chemistry, 2003 , vol. 1, # 21 p. 3758 - 3767

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被引用次数: 8

摘要

We describe two applications of silicon-tethered thermal allyl transfer reactions of α- silyloxyaldehydes; formally, these processes can be regarded as silatropic carbonyl ene reactions in which the silicon tether is transferred to the aldehyde oxygen concurrent with