Synthesis of retinals labelled with 13C in the cyclohexene ring

…, JML Courtin, JB Shadid, J Van Haveren…

文献索引：Gebhard, R.; Courtin, J. M. L.; Shadid, J. B.; Haveren, J. van; Haeringen, C. J. van; Lugtenburg, J. Recueil des Travaux Chimiques des Pays-Bas, 1989 , vol. 108, # 6 p. 207 - 214

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被引用次数: 16

摘要

Abstract In this paper we report the synthesis of five retinals, specifically mono-labelled with 13 C at the positions 1, 2, 3 and 4 and di-labelled with 13 C at the positions 16 and 17, with more than 98% chemical purity and high 13 C incorporation.(1-13 C)-and (16, 17-13 C 2) retinal were obtained in 20% overall yield from (2-13 C)-and (1, 3-13 C 2) acetone.(2-13 C)- and (3-13 C) retinal were prepared in 10% overall yield from (1-13 C)-and (2-13 C) ...