Azodioxide radical cations

…, H Sarker, ME Mendicino, SC Blackstock

文献索引：Greer, Melinda L.; Sarker, Haripada; Mendicino, Maria E.; Blackstock, Silas C. Journal of the American Chemical Society, 1995 , vol. 117, # 42 p. 10460 - 10467

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被引用次数: 24

摘要

Introduction Removing an electron from an organic molecule influences its molecular structure and dynamics, often dramatically. This is the basis for redox mediation of molecular reactivity, an important developing area of organic chemistry.'-4 One theme of organic redox chemistry is selective bond activation. Here, we report electron-transfer-mediated C,N bond activation in azoalkane dioxides and in nitrosoalkanes and report the fist direct observation of ...