Tetrahedron

Facile and catalytic degradation method of DDT using Pd/C–Et 3 N system under ambient pressure and temperature

Y Monguchi, A Kume, H Sajiki

文献索引：Monguchi, Yasunari; Kume, Akira; Sajiki, Hironao Tetrahedron, 2006 , vol. 62, # 35 p. 8384 - 8392

被引用次数: 30

摘要

The catalytic degradation method of p, p′-DDT [1, 1, 1-trichloro-2, 2-bis (p-chlorophenyl) ethane] and its regioisomer o, p′-DDT [1, 1, 1-trichloro-2-(o-chlorophenyl)-2-(p- chlorophenyl) ethane] using the Pd/C–Et3N system under ambient hydrogen pressure and temperature was established. The presence of Et3N was necessary for the quick and complete breakdown of DDT. The independent degradation study of two intermediates, p, ...

~66%

~23%

~14%

详细

~21%

详细

~0%

详细

~20%

~38%

详细

~99%

~30%

~73%

~53%

~21%

详细

~24%

详细

~4%

详细

~33%

~0%

详细

~12%

详细

~41%

详细

~99%

Carbon-Based Leaving Group in Substitution Reactions: Functi...

[Mahoney, Stuart J.; Lou, Tiantong; Bondarenko, Ganna; Fillion, Eric Organic Letters, 2012 , vol. 14, # 13 p. 3474 - 3477]

Electrochemical reduction and oxidation of DDT

[Merica, Simona G.; Jedral, Wojceich; Lait, Susan; Keech, Peter; Bunce, Nigel J. Canadian Journal of Chemistry, 1999 , vol. 77, # 7 p. 1281 - 1287]

THE CONDENSATION OF ACETYLENE WITH BENZENE AND ITS DERIVATIV...

[Cook; Chambers Journal of the American Chemical Society, 1921 , vol. 43, p. 336]

Electrolytic dechlorination of DDT in a bicontinuous microem...

[Schweizer, Silvia; Rusling, James F.; Huang, Qingdong Chemosphere, 1994 , vol. 28, # 5 p. 961 - 970]

Carbon-Based Leaving Group in Substitution Reactions: Functi...

[Mahoney, Stuart J.; Lou, Tiantong; Bondarenko, Ganna; Fillion, Eric Organic Letters, 2012 , vol. 14, # 13 p. 3474 - 3477]