The Journal of Organic Chemistry

3-Hydroxy-4-methylthiazole-2 (3H)-thione carbamates (TTOC carbamates). Useful precursors for monoalkylaminium cation radicals

M Newcomb, KA Weber

文献索引：Newcomb, Martin; Weber, Karl A. Journal of Organic Chemistry, 1991 , vol. 56, # 3 p. 1309 - 1313

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被引用次数: 28

摘要

Monoalkylaminium cation radicals have not been studied extensively. Neale and Marcus5 showed that monoalkylchloramines reacted in UV-initiated radical chain reactions under strongly acidic conditions (H2S04, AcOH) to give monoalkylaminium cation radicals that added to simple olefins. The ultimate products of the reactions, P-chloro amines, were obtained in fair to good yields. The products and yields were comparable to those ...