Platinum-Catalyzed Nucleophilic Addition of Vinylsilanes at the β-Position

…, H Sasagawa, H Kinoshita, J Ichikawa, A Hosomi

文献索引：Miura, Katsukiyo; Inoue, Gen; Sasagawa, Hisashi; Kinoshita, Hidenori; Ichikawa, Junji; Hosomi, Akira Organic Letters, 2009 , vol. 11, # 21 p. 5066 - 5069

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被引用次数: 12

摘要

In the presence of catalytic amounts of PtCl2 and metal iodides, β-substituted vinylsilanes reacted with aldehydes at the β-position to give allyl silyl ethers. The Pt-catalyzed addition to aromatic aldehydes proceeded efficiently in the presence of LiI. The combined use of PtCl2 and MnI2 was found to be effective in addition to aliphatic aldehydes.