Synthesis and kinetics of decomposition of di-tert-butyl tricarbonate, di-tert-butyl dithioltricarbonate, and the related dicarbonates

CS Dean, DS Tarbell…

文献索引：Dean,C.S. et al. Journal of Organic Chemistry, 1970 , vol. 35, p. 3393 - 3397

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被引用次数: 30

摘要

R= t-CIH9 butyl monocarbonate* 9 does not function as an intermediate, because, when the dicarbonate is decomposed in the presence of the monocarbonate, the monocarbonate remains unchanged in all respects. An authentic sample of di-t-butyl monocarbonate 9 was obtained from t-butyl carbonic diethylphosphoric anhydride9 8, by reaction with potassium t- butoxide (eq 4). t-Amyl t-butyl carbonate was prepared by the same procedure.