The Journal of Organic Chemistry

Synthesis and some reactions of 3, 3-dimethoxycylopropene

KB Baucom, GB Butler

文献索引：Baucom,K.B.; Butler,G.B. Journal of Organic Chemistry, 1972 , vol. 37, p. 1730 - 1732

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被引用次数: 44

摘要

During the course of attempts to synthesize compounds potentially capable of intramolecular charge-transfer interaction, an easy and relatively simple procedure for the preparation of 3, 3-dimethoxycyclopropene (IV) was developed. The starting material for this synthesis is the commercially available 2, 3-dichloropropene (I). Reaction of I with methanol and N- bromosuccinimide, using an acid catalyst, yields l-bromo-3-chloro-2, 2-dimethoxypropane ...