Stereoselectivity in 1, 4-elimination reactions. The gas-phase reactivity of deuterium-labeled 1-methoxy-2-cyclohexene and 6, 6-dimethyl-1-methoxy-2-cyclohexene
JJ Rabasco, SR Kass
文献索引：Rabasco, John J.; Kass, Steven R. Journal of Organic Chemistry, 1993 , vol. 58, # 9 p. 2633 - 2636
Elimination reactions are one of the most studied transformations in all of chemistry. Numerous aspects of the mechanism have been probed, and a tremendous wealth of information has been 0btained. l The selectivity in these processes is often influenced by solvation, aggregation, and counterion effects. The intrinsic reactivity, therefore, is of special interest. Ab initio molecular orbital calculations and gas-phase ion molecule investigations ...
