Stereodefined construction of trisubstituted alkenes by direct coupling reaction of allylating agents, alkynes, and organoboranes

…, D Takushima, H Satomura, G Onodera…

文献索引：Fukushima, Masahiro; Takushima, Daiki; Satomura, Hideaki; Onodera, Gen; Kimura, Masanari Chemistry - A European Journal, 2012 , vol. 18, # 26 p. 8019 - 8023

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被引用次数: 9

摘要

Stereodefined construction of CÀC multiple bonds through carbometallation is among the most challenging and significant synthetic strategies in organic and organometallic chemistry.[1] In particular, alkenylboranes are valuable and salient active species for the Suzuki–Miyaura cross-coupling reaction, which affords tri-and tetrasubstituted alkenes as efficient functional materials.[2] Therefore, highly regio-and stereocontrolled preparations ...