Tetrahedron Letters

Preparation of β-phenylnitroethanes having electron-donating aryl substitution

FA Luzzio, MT Wlodarczyk, DY Duveau, J Chen

文献索引：Luzzio, Frederick A.; Wlodarczyk, Marek T.; Duveau, Damien Y.; Chen, Juan Tetrahedron Letters, 2007 , vol. 48, # 38 p. 6704 - 6708

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被引用次数: 5

摘要

β-Phenyl-β-hydroxynitroethanes having activating aryl substituents are treated with triethylsilane/trifluoroacetic acid under solventless conditions to give the corresponding phenylnitroethanes. Substrates having no aryl substituents or substituents that are only mildly activating or deactivating do not result in appreciable conversion to the title compounds.