Tetrahedron

Cu-deposits on Mg metal surfaces promote electron transfer reactions

S Utsumi, T Katagiri, K Uneyama

文献索引：Utsumi, Shinya; Katagiri, Toshimasa; Uneyama, Kenji Tetrahedron, 2012 , vol. 68, # 4 p. 1085 - 1091

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被引用次数: 3

摘要

The enhancement of the electron transfer processes in the Grignard reagent formation-type ring silylation and the defluorination–silylation of perfluoroalkyl benzenes by Cu (0)- deposited Mg metal were confirmed. Microscopic analysis and substituent effects implied a different reduction process in the presence of Cu-deposited Mg metal than in the presence of bare Mg metal.