Reductive formation of disulfides from sulfenyl, sulfinyl, and sulfonyl derivatives using tri-n-propylamine and trichlorosilane

TH Chan, JP Montillier, WF Van Horn…

文献索引：Chan,T.H. et al. Journal of the American Chemical Society, 1970 , vol. 92, # 24 p. 7224 - 7225

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被引用次数: 30

摘要

a Sulfonate esters (X= Y= 0; 2= OR') do not react. All Starting material reactions were carried out in benzene solution. recovered. methyl benzenesulfinate (0.04 mol) and trichlorosilane (0.06 mol) in 70 ml of benzene at 20", tri-n-propylamine (0.042 mol) in 50 ml of benzene was added dropwise. After a stirring period of 4 hr, the mixture was hydrolyzed with water (20 ml) and extracted, affording an 85% yield of diphenyl disulfide. Similarly, disulfides were ...