Nucleophilic substitution reaction of benzyl bromide with N, N??Dimethylaniline: Significance of equilibrium cross??interaction constant

I Lee, YK Park, C Huh, HW Lee

文献索引：Lee, Ikchoon; Park, Yong Kyun; Huh, Chul; Lee, Hai Whang Journal of Physical Organic Chemistry, 1994 , vol. 7, # 10 p. 555 - 560

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被引用次数: 14

摘要

Abstract Kinetic studies on the reversible reactions of benzyl bromides with N, N- dimethylanilines were carried out for both the forward (kf) and reverse (kr) directions. The equilibrium constants, K were calculated using the ratio kf/kr and the equilibrium cross- interaction constant, ρ e XY was determined. The ρ e XY value was shown to represent a maximum intensity of interactions between substituents X and Y through covalent bonds ...