Tetrahedron

Synthesis of cyclic trithiocarbonates from cyclic ethers and carbon disulfide catalyzed by titanium complex

S Motokucho, D Takeuchi, F Sanda, T Endo

文献索引：Motokucho, Suguru; Takeuchi, Daisuke; Sanda, Fumio; Endo, Takeshi Tetrahedron, 2001 , vol. 57, # 33 p. 7149 - 7152

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被引用次数: 28

摘要

This work deals with reaction of oxetane derivatives with carbon disulfide in the presence of (2-propanolato) titanatrane. It afforded six-membered cyclic trithiocarbonates in good yields. Reaction of propylene oxide with carbon disulfide also proceeded in a similar manner to give a five-membered cyclic trithiocarbonate in excellent yield.