Introduction of functionalized mesopores to metal–organic frameworks via metal–ligand–fragment coassembly

…, ZU Wang, LB Sun, YP Chen, HC Zhou

文献索引：Park, Jinhee; Wang, Zhiyong U.; Sun, Lin-Bing; Chen, Ying-Pin; Zhou, Hong-Cai Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 20110 - 20116

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被引用次数: 86

摘要

Introduction of functionalized mesopores into microporous metal–organic frameworks (MOFs) can endow them with suitable properties for applications in gas storage, separation, catalysis, and drug delivery. However, common methods for functionalization (including pre- and post-synthetic modifications) of the internal surface of a MOF reduce the pore size of the MOF because the additional functional groups fill up the pores. We present a metal–ligand ...