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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Electron transfer process. 49. Radical and ionic reactions of (benzoylmethyl) mercurials

GA Russell, SV Kulkarni…

文献索引：Russell, Glen A.; Kulkarni, Shekhar V.; Khanna, Rajive K. Journal of Organic Chemistry, 1990 , vol. 55, # 3 p. 1080 - 1086

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被引用次数: 23

摘要

Photolysis of PhCOCHzHgCl or (PhCOCH,) 2Hg yields benzoylmethyl radicals which can be trapped by anions such as Me2C= N02-, RC (C02Et),-, RC (O-)= CH2 or by other electron- rich systems such as (RO) 3P, N-methylpyrrole, enamines, or norbornene. Electron transfer from the adduct radicals to the mercurial yields PhCOCHzA from the anions A-, PhCOCH, P (O)(OR), from P (OR) 3, and the phenacyl derivative from N-methylpyrrole or enamines. ...

丙二酸二乙酯结构式

丙二酸二乙酯

~%

diethyl 2-phenacylpropanedioate结构式

diethyl 2-phena...

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

未登录结构式

~27%

diethyl 2-phenacylpropanedioate结构式

diethyl 2-phena...

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

亚磷酸三甲酯结构式

亚磷酸三甲酯

~%

磷酸三甲酯结构式

磷酸三甲酯

1,2,3,4-Tetraphenyl-1,4-butanedione结构式

1,2,3,4-Tetraph...

详细

1-环己烯氧基三甲基硅烷结构式

1-环己烯氧基三甲基硅烷

~12%

2-(2-氧代-2-苯乙基)-环己酮结构式

2-(2-氧代-2-苯乙基)-环己酮

2-dimethoxyphosphoryl-1-phenylethanone结构式

2-dimethoxyphos...

苯乙酮结构式

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

亚磷酸三甲酯结构式

亚磷酸三甲酯

~%

磷酸三甲酯结构式

磷酸三甲酯

1,2,3,4-Tetraphenyl-1,4-butanedione结构式

1,2,3,4-Tetraph...

详细

1-环己烯氧基三甲基硅烷结构式

1-环己烯氧基三甲基硅烷

~%

2-(2-氧代-2-苯乙基)-环己酮结构式

2-(2-氧代-2-苯乙基)-环己酮

2-dimethoxyphosphoryl-1-phenylethanone结构式

2-dimethoxyphos...

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

亚磷酸三甲酯结构式

亚磷酸三甲酯

~%

1,2,3,4-Tetraphenyl-1,4-butanedione结构式

1,2,3,4-Tetraph...

氯甲烷结构式

详细

苯丙酮结构式

~%

2-methyl-1,4-diphenylbutane-1,4-dione结构式

2-methyl-1,4-di...

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

未登录结构式

~24%

2-methyl-1,4-diphenylbutane-1,4-dione结构式

2-methyl-1,4-di...

nitromethane结构式

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

~3%

3-nitro-1-phenylpropan-1-one结构式

3-nitro-1-pheny...

(nitromethyl)mercury(II) chloride结构式

(nitromethyl)me...

详细

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

diethyl methylmalonate anion结构式

diethyl methylm...

~59%

diethyl 2-methyl-2-phenacylpropanedioate结构式

diethyl 2-methy...

甲基丙二酸二乙酯结构式

甲基丙二酸二乙酯

~%

diethyl 2-methyl-2-phenacylpropanedioate结构式

diethyl 2-methy...

频那酮结构式

~%

5,5-二甲基-1-苯己烷-1,4-二酮结构式

5,5-二甲基-1-苯己烷-1,4-二酮

pinacolone enolate anion结构式

pinacolone enol...

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

~37%

5,5-二甲基-1-苯己烷-1,4-二酮结构式

5,5-二甲基-1-苯己烷-1,4-二酮

ethylnitronate(1-)结构式

ethylnitronate(1-)

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

~32%

未登录结构式

3-nitro-1-phenyl-butan-1-one结构式

3-nitro-1-pheny...

propane-2-nitronate结构式

propane-2-nitronate

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

~66%

Seneciophenone结构式

3-methyl-3-nitro-1-phenylbutan-1-one结构式

3-methyl-3-nitr...

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

亚磷酸三甲酯结构式

亚磷酸三甲酯

~13%

dimethyl 1-phenylethenyl phosphate结构式

dimethyl 1-phen...

未登录结构式

详细

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

亚磷酸三甲酯结构式

亚磷酸三甲酯

~67%

dimethyl 1-phenylethenyl phosphate结构式

dimethyl 1-phen...

苯乙酮结构式

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

~%

2-(2-氧代-2-苯乙基)-环己酮结构式

2-(2-氧代-2-苯乙基)-环己酮

1-环己烯氧基三甲基硅烷结构式

1-环己烯氧基三甲基硅烷

~12%

2-(2-氧代-2-苯乙基)-环己酮结构式

2-(2-氧代-2-苯乙基)-环己酮

2-dimethoxyphosphoryl-1-phenylethanone结构式

2-dimethoxyphos...

苯乙酮结构式

1-环己烯氧基三甲基硅烷结构式

1-环己烯氧基三甲基硅烷

~%

2-(2-氧代-2-苯乙基)-环己酮结构式

2-(2-氧代-2-苯乙基)-环己酮

2-dimethoxyphosphoryl-1-phenylethanone结构式

2-dimethoxyphos...

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

亚磷酸三乙酯结构式

亚磷酸三乙酯

~33%

1,2,3,4-Tetraphenyl-1,4-butanedione结构式

1,2,3,4-Tetraph...

(2-氧代-2-苯乙基)膦酸二乙酯结构式

(2-氧代-2-苯乙基)膦酸二乙酯

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

diphenylacetonitrile anion结构式

diphenylacetoni...

~70%

Butanedinitrile, 2,2,3,3-tetraphenyl-结构式

Butanedinitrile...

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

未登录结构式

~10%

Benzene,1,1'-(1-nitro-1,2-ethenediyl)bis-结构式

Benzene,1,1'-(1...

(1,2-dinitro-2-phenyl-ethyl)benzene结构式

(1,2-dinitro-2-...

详细

deoxybenzoin enolate结构式

deoxybenzoin enolate

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

~4%

1,2,3,4-Tetraphenyl-1,4-butanedione结构式

1,2,3,4-Tetraph...

1,2,4-三苯基-1,4-丁二酮结构式

1,2,4-三苯基-1,4-丁二酮

(2-oxo-2-phenylethyl)mercury chloride结构式

(2-oxo-2-phenyl...

~4%

1,2,3,4-Tetraphenyl-1,4-butanedione结构式

1,2,3,4-Tetraph...

1,2,4-三苯基-1,4-丁二酮结构式

1,2,4-三苯基-1,4-丁二酮

二苯乙酮结构式

~%

1,2,4-三苯基-1,4-丁二酮结构式

1,2,4-三苯基-1,4-丁二酮

Carbon–carbon bond formation by radical addition–fragmentati...

[Cai, Yudong; Roberts, Brian P.; Tocher, Derek A.; Barnett, Sarah A. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 17 p. 2517 - 2529]

Radical Alkylations of Alkyl Halides and Unactivated CH Bond...

[Lee, Jin Young; Lim, Kyoung-Chan; Meng, Xiangjian; Kim, Sunggak Synlett, 2010 , # 11 p. 1647 - 1650]

Carbon–carbon bond formation by radical addition–fragmentati...

[Cai, Yudong; Roberts, Brian P.; Tocher, Derek A.; Barnett, Sarah A. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 17 p. 2517 - 2529]

Reaction of aryl chromium carbene complexes with ethyl propi...

[Yamashita, Ayako; Scahill, Terrence A. Tetrahedron Letters, 1982 , vol. 23, # 37 p. 3765 - 3768]