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Photosensitized oxygenation of diaryl tellurides to telluroxides and their oxidizing properties

…, M Endo, K Nishiyama, A Ouchi, W Ando

文献索引:Oba, Makoto; Endo, Masaki; Nishiyama, Kozaburo; Ouchi, Akihiko; Ando, Wataru Chemical Communications, 2004 , # 14 p. 1672 - 1673

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被引用次数: 9

摘要

Recently, along with public awareness of environmental issues there is growing need for the introduction of clean synthesis. The necessity for a better reagent for oxidation reactions in organic synthesis led us to introduce here bulky diaryl telluroxides which, due to the weak tellurium–oxygen bond, are expected to efficiently transfer the oxygen atom to organic substrates. Diaryl telluroxides, in particular 4,4′-dimethoxydiphenyl telluroxide 2c, are recognized as mild ...