Mendeleev Communications

o-Iodoxybenzoic acid in dimethylformamide as a convenient reagent for the oxidation of alcohols to aldehydes and ketones

MA Lapitskaya, LL Vasiljeva, KK Pivnitsky

文献索引：Lapitskaya, Margarita A.; Vasiljeva, Ljudmila L.; Pivnitsky, Kasimir K. Mendeleev Communications, 2008 , vol. 18, # 6 p. 309 - 311

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被引用次数: 14

摘要

DMF dissolves o-iodoxybenzoic acid (up to 0.1 mol dm− 3) and, therefore, is a solvent of choice for the reactions with o-iodoxybenzoic acid simplifying significantly a product isolation procedure due to a higher volatility. The reaction rate and selectivity of the oxidation of alcohols to corresponding carbonyl compounds with o-iodoxybenzoic acid in DMF are close to those in DMSO.