Synthesis and thermal decomposition of tertiary β??nitroalkyl peroxynitrates

EFJ Duynstee, J Hennekens…

文献索引：Duynstee,E.F.J. et al. Recueil des Travaux Chimiques des Pays-Bas, 1973 , vol. 92, p. 1272 - 1280

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被引用次数: 3

摘要

Abstract Three tertiary β-nitroalkyl peroxynitrates 2a, 2b and 2c were prepared by reaction of N 2 O 4 and excess O 2 with isobutene (la), 2, 3, 3-trimethyl-2-butene (1b) and 2, 3-dimethyl- 2-butene (1c), respectively. These compounds are rather unstable and at 23 slow decomposition occurs. It seems likely that this decomposition starts by OO bond fission yielding an NO 3 radical and a β-nitroalkoxy radical. In the case of 2a this alkoxy radical ...