Tetrahedron letters

An efficient of Grignard-type procedure for the preparation of gem-diallylated compound

KH Shen, CW Kuo, CF Yao

文献索引：Shen, Kao-Hsien; Kuo, Chun-Wei; Yao, Ching-Fa Tetrahedron Letters, 2007 , vol. 48, # 36 p. 6348 - 6351

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被引用次数: 13

摘要

An efficient and a new procedure for the conversion of various carboxylic acid derivatives into the corresponding gem-diallylated compound under mild reaction condition has been developed. The triallylaluminum mediated Grignard-type addition of carboxylic acid derivative was utilized as a key operation to affect the transformation. The procedure is operationally simple, giving good to excellent product yields for a broad range of ...