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Journal of organometallic chemistry

An efficient construction of bicyclic systems containing a seven-membered ring by tandem ring-closing metathesis reactions of dienynes

FD Boyer, I Hanna

文献索引:Boyer, Francois-Didier; Hanna, Issam Journal of Organometallic Chemistry, 2006 , vol. 691, # 24-25 p. 5181 - 5188

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被引用次数: 0

摘要

Various (5–7) and (6–7) bicyclic dienes bearing quaternary methyl group and ester functionality have been synthesized from acyclic dienynes by tandem ring-closing metathesis (RCM) reaction. Epoxidation of these conjugated dienes led to bicyclic vinyl oxiranes which undergo acid-catalyzed addition of alcohols to afford highly oxygenated compounds.