Synthesis and chemistry of aryloxygermylene-amine complexes

E Bonnefille, S Mazières, N El Hawi, H Gornitzka…

文献索引：Bonnefille, Eric; Mazieres, Stephane; Hawi, Nancy El; Gornitzka, Heinz; Couret, Claude Journal of Organometallic Chemistry, 2006 , vol. 691, p. 5619 - 5625

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被引用次数: 11

摘要

The synthesis of stable monomeric dimesityloxygermylene-amine (MesO) 2Ge-NR3 [NR3= Et2NH,(C6H11) 2NH, Et3N, dabco, tmeda] and chloromesityloxygermylene-amine MesO (Cl) Ge–tmeda complexes is presented. All compounds have been fully characterized by spectroscopic methods. The insertion reaction of (MesO) 2Ge–tmeda 1a with dimethyl disulfide, bis (trimethylsilyl) peroxide and iodomethane is reported. Cycloaddition ...