Organometallics

Palladium-catalyzed addition of hexamethylditin to allenes

H Killing, TN Mitchell

文献索引：Killing, Hubertus; Mitchell, Terence N. Organometallics, 1984 , vol. 3, p. 1318 - 1320

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被引用次数: 46

摘要

Summary: Hexamethylditin adds readily to allenes in the presence of Pd (PPh3),; unsymmetrically substituted allenes undergo kinetically controlled addition at lower temperatures, while at higher temperatures the thermodynamically more stable products are formed.