Protodesilylation of 2, 6-Disubstituted Silyphosphinines. Experimental and Theoretical Study

…, M Fustier, N Mézailles, P Le Floch

文献索引：Blug, Matthias; Piechaczyk, Olivier; Fustier, Marie; Mezailles, Nicolas; Le Floch, Pascal Le Journal of Organic Chemistry, 2008 , vol. 73, # 8 p. 3258 - 3261

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被引用次数: 3

摘要

Phosphinines 1-3 are one of the most important classes of phosphorus aromatic heterocycles with phospholes 4 and their anionic derivatives. Due to their very specific electronic properties, that strongly differ from that of classical phosphines and related nitrogen heterocycles, they have found applications as ligands in coordination chemistry for the stabilization of highly reduced complexes 5,6 and in homogeneous catalysis such as the ...