Synthesis

A New Synthesis of 6b, 8, 9, 10, 11, 11a-Hexahydro-7H-acenaphthylenes by Base-Catalyzed Photocyclization of 1-Arylcycloheptenes

R Lapouyade, A Nourmamode

文献索引：Lapouyade, Rene; Nourmamode, Aziz Synthesis, 1984 , # 2 p. 161 - 164

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被引用次数: 2

摘要

Communications 161 one of the most exploited methods for the synthesis of poly-cyclic aromatic hydrocarbons of the phene series. This reaction is very selective and the sum of the free valence numbers of the involved atoms r and s in the excited state molecule, Zl=';*; _, has been found to be a very reliable parameter for pre-dicting the cyclization mode '.