Journal of the American Chemical Society

Attempts to Prepare Optically Active Ethyleneimine Derivatives Containing an Asymmetric Nitrogen Atom

R Adams, TL Cairns

文献索引：Adams; Cairns Journal of the American Chemical Society, 1939 , vol. 61, p. 2464,2466

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被引用次数: 13

摘要

The fact that many oximes exist in stable syn-and anti-forms and that the oxime of cyclohexanone-4-carboxylic acid2 can be resolved has led to the belief that, in these compounds, the nitrogen atom probably exists in a stable tetrahedral form. The work of Meisenheimer3 has established that many substituted hydroxylamines of the type RR'NOH cannot be resolved and the investigations of many others have failed to find an optically- ...