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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Tetrahedron

Synthesis of thromboxane A 2 analogs—4:(±)-Dithiathromboxane A2 sodium salt

S Ohuchida, N Hamanaka, M Hayashi

文献索引：Ohuchida, Shuichi; Hamanaka, Nobuyuki; Hayashi, Masaki Tetrahedron, 1983 , vol. 39, # 24 p. 4273 - 4280

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被引用次数: 11

摘要

In the preceding papers'** we have described the syn- theses of thiathromboxane A2 possessing one sulfur atom in the bicycle [3.1.1] heptane skeleton. In this article is described the total synthesis of the sodium salt 1 of dithiathromboxane A2 which contains two sulfur atoms in the main framework, bicycle-[3.l.llheptane ring.' ... In the synthesis of 1 the most important problem was the construction of 2,6 - dithiabicyclo[3.1.l]heptane skeleton. To the best of our ...

6-chlorohex-2-yn-1-ol结构式

6-chlorohex-2-y...

甲基磺酰氯结构式

甲基磺酰氯

~%

6-chlorohex-2-yn-1-ol,methanesulfonic acid结构式

6-chlorohex-2-y...

6-chlorohex-2-yn-1-ol结构式

6-chlorohex-2-y...

~%

methyl 8-chloro-2-(2,2-dimethoxyacetyl)oct-4-ynoate结构式

methyl 8-chloro...

6-chlorohex-2-yn-1-ol,methanesulfonic acid结构式

6-chlorohex-2-y...

~%

methyl 8-chloro-2-(2,2-dimethoxyacetyl)oct-4-ynoate结构式

methyl 8-chloro...

6-chlorohex-2-yn-1-ol结构式

6-chlorohex-2-y...

~%

methyl 8-formyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-formyl...

6-chlorohex-2-yn-1-ol,methanesulfonic acid结构式

6-chlorohex-2-y...

~%

methyl 8-formyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-formyl...

methyl 8-chloro-2-(1-hydroxy-2,2-dimethoxyethyl)oct-4-ynoate结构式

methyl 8-chloro...

~%

methyl 8-formyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-formyl...

methyl (Z)-8-formyl-10,10-dimethoxy-9-((methylsulfonyl)oxy)dec-5-enoate结构式

methyl (Z)-8-fo...

~%

methyl 8-formyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-formyl...

methyl (Z)-8-(hydroxymethyl)-10,10-dimethoxy-9-((methylsulfonyl)oxy)dec-5-enoate结构式

methyl (Z)-8-(h...

~%

methyl 8-formyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-formyl...

methyl (5Z,8E)-8-(1-hydroxyethyl)-10,10-dimethoxydeca-5,8-dienoate结构式

methyl (5Z,8E)-...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

4,4-二甲氧基乙酰乙酸甲酯结构式

4,4-二甲氧基乙酰乙酸甲酯

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

6-chlorohex-2-yn-1-ol结构式

6-chlorohex-2-y...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

6-chlorohex-2-yn-1-ol,methanesulfonic acid结构式

6-chlorohex-2-y...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

methyl 8-chloro-2-(1-hydroxy-2,2-dimethoxyethyl)oct-4-ynoate结构式

methyl 8-chloro...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

6-chloro-1-iodohex-2-yne结构式

6-chloro-1-iodo...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

2-(6-chlorohex-2-yn-1-yl)-4,4-dimethoxybutane-1,3-diol结构式

2-(6-chlorohex-...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

methyl 9-hydroxy-8-(hydroxymethyl)-10,10-dimethoxydec-5-ynoate结构式

methyl 9-hydrox...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

methyl 8-chloro-2-(2,2-dimethoxyacetyl)oct-4-ynoate结构式

methyl 8-chloro...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

acetic acid,2-(6-chlorohex-2-ynyl)-4,4-dimethoxybutane-1,3-diol结构式

acetic acid,2-(...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

[2-(1-acetyloxy-2,2-dimethoxyethyl)-8-cyanooct-4-ynyl] acetate结构式

[2-(1-acetyloxy...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

methyl (Z)-8-(hydroxymethyl)-10,10-dimethoxy-9-((methylsulfonyl)oxy)dec-5-enoate结构式

methyl (Z)-8-(h...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

methyl (Z)-8-formyl-10,10-dimethoxy-9-((methylsulfonyl)oxy)dec-5-enoate结构式

methyl (Z)-8-fo...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

methyl (Z)-9-hydroxy-8-(hydroxymethyl)-10,10-dimethoxydec-5-enoate结构式

methyl (Z)-9-hy...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

methyl 8-formyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-formyl...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

(Z)-2-(1-hydroxy-2,2-dimethoxyethyl)-9-methoxy-9-oxonon-4-en-1-yl benzoate结构式

(Z)-2-(1-hydrox...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

(Z)-2-(2,2-dimethoxy-1-((methylsulfonyl)oxy)ethyl)-9-methoxy-9-oxonon-4-en-1-yl benzoate结构式

(Z)-2-(2,2-dime...

~%

methyl 8-acetyl-10,10-dimethoxydeca-5,8-dienoate结构式

methyl 8-acetyl...

6-chlorohex-2-yn-1-ol,methanesulfonic acid结构式

6-chlorohex-2-y...

~%

6-chloro-1-iodohex-2-yne结构式

6-chloro-1-iodo...

6-chlorohex-2-yn-1-ol结构式

6-chlorohex-2-y...

~%

6-chloro-1-iodohex-2-yne结构式

6-chloro-1-iodo...

2-(6-chlorohex-2-yn-1-yl)-4,4-dimethoxybutane-1,3-diol结构式

2-(6-chlorohex-...

乙酰氯结构式

~%

acetic acid,2-(6-chlorohex-2-ynyl)-4,4-dimethoxybutane-1,3-diol结构式

acetic acid,2-(...

6-chlorohex-2-yn-1-ol结构式

6-chlorohex-2-y...

~%

acetic acid,2-(6-chlorohex-2-ynyl)-4,4-dimethoxybutane-1,3-diol结构式

acetic acid,2-(...

6-chlorohex-2-yn-1-ol,methanesulfonic acid结构式

6-chlorohex-2-y...

~%

acetic acid,2-(6-chlorohex-2-ynyl)-4,4-dimethoxybutane-1,3-diol结构式

acetic acid,2-(...

methyl 8-chloro-2-(1-hydroxy-2,2-dimethoxyethyl)oct-4-ynoate结构式

methyl 8-chloro...

~%

acetic acid,2-(6-chlorohex-2-ynyl)-4,4-dimethoxybutane-1,3-diol结构式

acetic acid,2-(...

氰化钠结构式

acetic acid,2-(6-chlorohex-2-ynyl)-4,4-dimethoxybutane-1,3-diol结构式

acetic acid,2-(...

~79%

[2-(1-acetyloxy-2,2-dimethoxyethyl)-8-cyanooct-4-ynyl] acetate结构式

[2-(1-acetyloxy...

6-chlorohex-2-yn-1-ol结构式

6-chlorohex-2-y...

~%

[2-(1-acetyloxy-2,2-dimethoxyethyl)-8-cyanooct-4-ynyl] acetate结构式

[2-(1-acetyloxy...

methyl 8-chloro-2-(1-hydroxy-2,2-dimethoxyethyl)oct-4-ynoate结构式

methyl 8-chloro...

~%

[2-(1-acetyloxy-2,2-dimethoxyethyl)-8-cyanooct-4-ynyl] acetate结构式

[2-(1-acetyloxy...

6-chlorohex-2-yn-1-ol,methanesulfonic acid结构式

6-chlorohex-2-y...

~%

[2-(1-acetyloxy-2,2-dimethoxyethyl)-8-cyanooct-4-ynyl] acetate结构式

[2-(1-acetyloxy...