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Synthesis

Stereoselective total synthesis of (+)-Virol C

G Sabitha, CS Reddy, P Srihari, JS Yadav

文献索引:Sabitha, Gowravaram; Reddy, Ch. Srinivas; Srihari, Pabbaraja; Yadav, Jhillu Singh Synthesis, 2003 , # 17 p. 2699 - 2704

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被引用次数: 8

摘要

Abstract A highly stereoselective synthesis of (+)-Virol C (1) has been achieved starting from octan-1-ol (6) using two different strategies, elimination reactions of epoxyallyl chloride 12 and epoxy chloride 16 to hydroxyenyne 2 and trans-hydroxyalkenyl chloride 4 as key reactions in route a and route b, respectively.