A stable halosilylene at room temperature in THF solution

…, HM Cho, MS Ryu, CH Kim, W Ando

文献索引：Myong Euy Lee; Hyeon Mo Cho; Min Seong Ryu; Chang Hwan Kim; Ando Journal of the American Chemical Society, 2001 , vol. 123, # 31 p. 7732 - 7733

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被引用次数: 22

摘要

Silylenes, corresponding to carbenes in organic chemistry, are important intermediates in photochemical, thermal, and metalreduction reactions of organosilicon compounds. 1 Among various substituted silylenes, there are several reports of halosilylenes. In most cases, halosilylenes have been generated in the gaseous state by thermolysis reactions and identified by trapping reactions2 or observed as short-lived species by spectroscopic ...