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Polyfluoro-compounds based on the cycloheptane ring system. Part 5. Octafluordcyclohepta-1, 3, 5-triene and hexafluorotropone

DJ Dodsworth, CM Jenkins, R Stephens…

文献索引:Dodsworth, D. J.; Jenkins, C. M.; Stephens, R.; Tatlow, J. C. Journal of Fluorine Chemistry, 1984 , vol. 24, p. 41 - 60

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被引用次数: 16

摘要

Abstract Decafluorocyclohepta-l, 3-diene underwent reductive addition-elimination with sodium borohydride to give mainly 1H-nonafluorocyclohepta-1, 3-diene, together with minor products, the 1H, 4H-octafluoro-analogue and, most significantly, 5H-nonafluorocyclohepta- l, 3-diene. Decafluorocyclohepta-l, 4-diene similarly gave mainly a mixture of 1H-and 2H- nonafluorocyclohepta-l, 4-diene, together with some 6H-nonafluorocyclohepta-l, 4-diene ...

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