Metallacarboranes in catalysis. 6. Kinetics and mechanism of alkene hydrogenation and isomerization catalyzed by rhodacarborane clusters. A search for cluster …

PE Behnken, JA Belmont, DC Busby…

文献索引：Behnken, Paul E.; Belmont, James A.; Busby, David C.; Delaney, Mark S.; King, Roswell E.; et al. Journal of the American Chemical Society, 1984 , vol. 106, p. 3011 - 3025

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被引用次数: 66

摘要

Results Scope of the Investigation and Kinetic Methods. The investigation reported here includes kinetic, deuterium-labeling, and reaction product studies of representative terminal alkene hydrogenation and isomerization reactions. Previous experience had shown that nonterminal alkenes were sluggish in hydrogenation reactions carried out with our catalyst precursors in the presence of added PPh, and that 1-alkenes which were capable of ...