Russian Chemical Bulletin

Some features of an SmI2−(Me2N) 3P—THF system. Transformation of esters into dimethylamides

NA Ivanova, AM Shainurova, MS Miftakhov

文献索引：Ivanova; Shainurova; Miftakhov Russian Chemical Bulletin, 2000 , vol. 49, # 2 p. 329 - 331

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摘要

Stall-intermediates generated upon addition of (MezN)3P to a solution of Sml~ in THF exhibit the properties of a single-electron reducing agent and an N-nucleophite. In particular, N,N-dimethylamides are formed from esters. Key words: esters, samarium diiodide,