Synthesis of substituted cyclopentadienes: intramolecular Diels-Alder precursors

DD Sternbach, JW Hughes…

文献索引：Sternbach, Daniel D.; Hughes, Jeffrey W.; Burdi, Douglas F. Journal of Organic Chemistry, 1984 , vol. 49, # 1 p. 201 - 202

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被引用次数: 10

摘要

In the course of developing a versatile synthetic route to natural products containing more than one five-membered carbocyclic ring (polyquinanes) we needed a general route to cyclopentadienes substituted with functionalized alkenyl chains. These compounds can serve as precursors for intramolecular Diels-Alder reacti0ns. l Two complementary routes to substituted cyclopentadienea may be envisioned (eq 1). Route A represents the well- ...