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Journal of the American Chemical Society

The Action of Organomagnesium Halides on α, β-Unsaturated Aldehydes

PG Stevens

文献索引:Stevens Journal of the American Chemical Society, 1935 , vol. 57, p. 1115

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被引用次数: 9

摘要

The action of organomagnesium halides on a, 8-unsaturated aldehydes has been the subject of many investigations. Grignard, the pioneer in this field, obtained only secondary carbinols. Thereafter came a host of investigators who likewise obtained only secondary carbinols or degradation products derived from them. Very few, however, attempted to detect any product other than that formed by 1, 2 addition. Kohler, 2 the first of these, treated ...